Ferrocene derivatives as receptors to explore ammonium cation-π interactions

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dc.contributor.authorHu J.
dc.contributor.authorBarbour L.J.
dc.contributor.authorGokel G.W.
dc.date.accessioned2011-05-15T16:05:16Z
dc.date.available2011-05-15T16:05:16Z
dc.date.issued2004
dc.description.abstractThe potential importance in biology of ammonium-arene cation-π interactions has fostered the development of a model system that uses ferrocene as a scaffold that can rotate groups with respect to each other while maintaining them at a fixed distance. The preparation of 1-benzyl-1′-N,N- dimethylaminomethylferrocene methiodide is reported along with the solid state structure of it and its precursor. Clear evidence is presented for an intermolecular ammonium-arene interaction. The results are analyzed in the context of existing arene-ammonium ion contacts.
dc.description.versionArticle
dc.identifier.citationNew Journal of Chemistry
dc.identifier.citation28
dc.identifier.citation8
dc.identifier.issn11440546
dc.identifier.other10.1039/b313422a
dc.identifier.urihttp://hdl.handle.net/10019.1/13048
dc.subject1 benzyl 1' n,n dimethylaminomethylferrocene methiodide
dc.subjectammonia
dc.subjectcation
dc.subjectferrocene derivative
dc.subjectpolycyclic aromatic hydrocarbon
dc.subjectreceptor
dc.subjectunclassified drug
dc.subjectarticle
dc.subjectcation pi interaction
dc.subjectchemical structure
dc.subjectmolecular interaction
dc.subjectmolecular model
dc.subjectpriority journal
dc.subjectrotation
dc.subjectsolid state
dc.subjectsynthesis
dc.titleFerrocene derivatives as receptors to explore ammonium cation-π interactions
dc.typeArticle
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