Catena-Poly[copper(I)-bis(μ-trifluoro-methane-sulfonato-k2 O:O′)-copper(I)-bis(μ-trimethyl trithio-phosphite)-k2 P:S;k2 S:P]
dc.contributor.author | Strasser C.E. | |
dc.contributor.author | Cronje S. | |
dc.contributor.author | Raubenheimer H.G. | |
dc.date.accessioned | 2011-05-15T15:56:18Z | |
dc.date.available | 2011-05-15T15:56:18Z | |
dc.date.issued | 2008 | |
dc.description.abstract | The title compound, [Cu2(CF3SO3)2(C3H9PS3)2] n , crystallizes as infinite chains in which two trimethyl trithio-phosphite ligands and two trifluoro-methane-sulfonate anions bridge the essentially tetra-hedrally coordinated CuI ions in an alternating fashion. The P and one S atom of each trimethyl trithio-phosphite ligand are employed for coordination. The mol-ecular structure exhibits the rare motif of copper(I) bridged by two trifluoro-methane-sulfonate anions generating eight-membered rings. | |
dc.description.version | Article | |
dc.identifier.citation | Acta Crystallographica Section E: Structure Reports Online | |
dc.identifier.citation | 65 | |
dc.identifier.citation | 1 | |
dc.identifier.issn | 16005368 | |
dc.identifier.other | 10.1107/S1600536808041809 | |
dc.identifier.uri | http://hdl.handle.net/10019.1/9777 | |
dc.subject | Tetra | |
dc.subject | Trifluoro | |
dc.title | Catena-Poly[copper(I)-bis(μ-trifluoro-methane-sulfonato-k2 O:O′)-copper(I)-bis(μ-trimethyl trithio-phosphite)-k2 P:S;k2 S:P] | |
dc.type | Article |