1,3-Benzothia-zolium tetra-chlorido-aurate(III) tetra-hydro-furan solvate

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dc.contributor.authorHagos T.K.
dc.contributor.authorNogai S.D.
dc.contributor.authorDobrzaska L.
dc.contributor.authorCronje S.
dc.contributor.authorRaubenheimer H.G.
dc.date.accessioned2011-05-15T15:56:18Z
dc.date.available2011-05-15T15:56:18Z
dc.date.issued2009
dc.description.abstractIn the crystal structure of the title ionic compound (C7H 6NS)[AuCl4]·C4H8O, the [AuCl4]- anion shows a typical square-planar geometry. Numerous weak C - H⋯Cl hydrogen bonds between [AuCl4] - and the 1,3-benzothia-zolium units form layers comprised of 24-membered rings in which hydrogen-bonded tetra-hydro-furan (THF) solvent mol-ecules are accommodated. C - H⋯Cl inter-actions between THF and [AuCl4]- from adjacent layers result in bilayers. These are further stabilized by π-π inter-actions between the thia-zole and benzene rings [centroid-centroid distance = 3.971 (3) Å], resulting in the formation of a three-dimensional supra-molecular assembly.
dc.description.versionArticle
dc.identifier.citationActa Crystallographica Section E: Structure Reports Online
dc.identifier.citation65
dc.identifier.citation3
dc.identifier.issn16005368
dc.identifier.other10.1107/S1600536809003572
dc.identifier.urihttp://hdl.handle.net/10019.1/9772
dc.subjectTetra
dc.subjectThia
dc.title1,3-Benzothia-zolium tetra-chlorido-aurate(III) tetra-hydro-furan solvate
dc.typeArticle
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