Tuning extreme anisotropic thermal expansion in 1D coordination polymers through metal selection and solid solutions†

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dc.contributor.authorVan Wyk, Lisa M.en_ZA
dc.contributor.authorLoots, Leighen_ZA
dc.contributor.authorBarbour, Leonard J.en_ZA
dc.date.accessioned2023-05-11T07:18:03Zen_ZA
dc.date.available2023-05-11T07:18:03Zen_ZA
dc.date.issued2021-07en_ZA
dc.descriptionCITATION: Van Wyk, L. M., Loots, L. & Barbour, L. J. 2021. Tuning extreme anisotropic thermal expansion in 1D coordination polymers through metal selection and solid solutions†. Chemical Science 57(6):4 pages. doi.org/10.1039/D1CC01717Aen_ZA
dc.descriptionThe original publication is available at: rsc.orgen_ZA
dc.description.abstractThe thermal expansion behaviour of a series of 1D coordination polymers has been investigated. Variation of the metal centre allows tuning of the thermal expansion behaviour from colossal positive volumetric to extreme anomalous thermal expansion. Preparation of solid solutions increased the magnitude of the anomalous thermal expansion further, producing two species displaying supercolossal anisotropic thermal expansion (ZnCoCPHTαY2 = −712 MK−1, αY3 = 1632 MK−1 and ZnCdCPHTαY2 = −711 MK−1, αY3 = 1216 MK−1).en_ZA
dc.description.versionPublisher’s versionen_ZA
dc.format.extent4 pagesen_ZA
dc.identifier.citationVan Wyk, L. M., Loots, L. & Barbour, L. J. 2021. Tuning extreme anisotropic thermal expansion in 1D coordination polymers through metal selection and solid solutions†. Chemical Science 57(6):4 pages. doi.org/10.1039/D1CC01717Aen_ZA
dc.identifier.issn2041-6539 (Online)en_ZA
dc.identifier.otherdoi.10.1039/D1CC01717Aen_ZA
dc.identifier.urihttp://hdl.handle.net/10019.1/126896en_ZA
dc.language.isoen_ZAen_ZA
dc.publisherRoyal Society of Chemistryen_ZA
dc.rights.holderAuthors retain copyrighten_ZA
dc.subjectExpansion (Heat)en_ZA
dc.subjectCoordination polymersen_ZA
dc.subjectSolutions, Soliden_ZA
dc.subjectMetal selectionen_ZA
dc.titleTuning extreme anisotropic thermal expansion in 1D coordination polymers through metal selection and solid solutions†en_ZA
dc.typeArticleen_ZA
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