Tuning extreme anisotropic thermal expansion in 1D coordination polymers through metal selection and solid solutions†
Date
2021-07
Journal Title
Journal ISSN
Volume Title
Publisher
Royal Society of Chemistry
Abstract
The thermal expansion behaviour of a series of 1D coordination polymers has been investigated. Variation of the metal centre allows tuning of the thermal expansion behaviour from colossal positive volumetric to extreme anomalous thermal expansion. Preparation of solid solutions increased the magnitude of the anomalous thermal expansion further, producing two species displaying supercolossal anisotropic thermal expansion (ZnCoCPHTαY2 = −712 MK−1, αY3 = 1632 MK−1 and ZnCdCPHTαY2 = −711 MK−1, αY3 = 1216 MK−1).
Description
CITATION: Van Wyk, L. M., Loots, L. & Barbour, L. J. 2021. Tuning extreme anisotropic thermal expansion in 1D coordination polymers through metal selection and solid solutions†. Chemical Science 57(6):4 pages. doi.org/10.1039/D1CC01717A
The original publication is available at: rsc.org
The original publication is available at: rsc.org
Keywords
Expansion (Heat), Coordination polymers, Solutions, Solid, Metal selection
Citation
Van Wyk, L. M., Loots, L. & Barbour, L. J. 2021. Tuning extreme anisotropic thermal expansion in 1D coordination polymers through metal selection and solid solutions†. Chemical Science 57(6):4 pages. doi.org/10.1039/D1CC01717A