Cadmium(II) complexes of N,N-diethyl-N′-benzoylthio(seleno)urea as single-source precursors for the preparation of CdS and CdSe nanoparticles

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dc.contributor.authorBruce J.C.
dc.contributor.authorRevaprasadu N.
dc.contributor.authorKoch K.R.
dc.date.accessioned2011-05-15T16:05:15Z
dc.date.available2011-05-15T16:05:15Z
dc.date.issued2007
dc.description.abstractCadmium complexes of N,N-diethyl-N′-benzoylthiourea and N,N-diethyl-N′-benzoylselenourea have been used as single-source precursors for the synthesis of HDA capped CdS and CdSe nanoparticles in a predominantly cubic phase, respectively. Both types of particles show quantum confinement effects and close to band edge luminescence. The particle morphology of CdS and CdSe nanoparticles obtained from the thermolysis of bis[N,N-diethyl-N′-(benzoylthioureato)]cadmium(II) and bis[N,N-diethyl-N′-(benzoylselenoureato)]cadmium(II) was found to be independent of the thermolysis temperature and monomer concentration in the ranges examined. The structure of the N,N-diethyl-N′-benzoylthiourea ligand was determined by single-crystal X-ray diffraction. © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique.
dc.description.versionArticle
dc.identifier.citationNew Journal of Chemistry
dc.identifier.citation31
dc.identifier.citation9
dc.identifier.issn11440546
dc.identifier.other10.1039/b618254b
dc.identifier.urihttp://hdl.handle.net/10019.1/13043
dc.subjectcadmium
dc.subjectmonomer
dc.subjectn,n diethyl n benzoylthioselenourea
dc.subjectnanoparticle
dc.subjectunclassified drug
dc.subjecturea derivative
dc.subjectarticle
dc.subjectcrystal structure
dc.subjectluminescence
dc.subjectpriority journal
dc.subjectquantum chemistry
dc.subjecttemperature sensitivity
dc.subjectX ray diffraction
dc.titleCadmium(II) complexes of N,N-diethyl-N′-benzoylthio(seleno)urea as single-source precursors for the preparation of CdS and CdSe nanoparticles
dc.typeArticle
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