(Pentafluoropropionato-κO)tetrakis(trimethylphosphine oxide-κO)copper(II) pentafluoropropionate

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dc.contributor.authorSzymanska I.B.
dc.contributor.authorDobrzanska L.
dc.date.accessioned2011-10-13T16:58:09Z
dc.date.available2011-10-13T16:58:09Z
dc.date.issued2011
dc.description.abstractThe title compound, [Cu(C3F5O2)(C 3H9OP)4](C3F5O 2), comprises a cationic CuII complex and a disordered pentafluoropropionate counterion. The metal atom has a distorted squarepyramidal coordination environment formed by four O atoms originating from trimethylphosphine oxide molecules and the remaining one belonging to the monodentate pentafluoropropionate anion, which is situated in the basal plane of the pyramid. The molecules are held together in the crystal by a net of weak C - H⋯O and C - H⋯F hydrogen bonds. The counter anion is disordered over two sets of sites in a 0.629 (5):0.371 (5) ratio.
dc.description.versionArticle
dc.identifier.citationActa Crystallographica Section E: Structure Reports Online
dc.identifier.citation67
dc.identifier.citation9
dc.identifier.citationhttp://www.scopus.com/inward/record.url?eid=2-s2.0-80052655315&partnerID=40&md5=48cfcbaa284bf365ec67077177c58381
dc.identifier.issn16005368
dc.identifier.other10.1107/S1600536811031114
dc.identifier.urihttp://hdl.handle.net/10019.1/16627
dc.title(Pentafluoropropionato-κO)tetrakis(trimethylphosphine oxide-κO)copper(II) pentafluoropropionate
dc.typeArticle
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