Mono- en dikernige karbeenkomplekse van Mn(I) en W(O)

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dc.contributor.advisorRaubenheimer, H. G.en_ZA
dc.contributor.authorNeveling, Arnoen_ZA
dc.contributor.otherStellenbosch University. Faculty of Science. Dept. of Chemistry & Polymer Science.
dc.date.accessioned2012-08-27T14:03:49Z
dc.date.available2012-08-27T14:03:49Z
dc.date.issued1999-12
dc.descriptionThesis (M.Sc.) -- University of Stellenbosch, 1999.
dc.description.abstractENGLISH SUMMARY: In the first part of this thesis zirconocene complexes with anionic Mn(I) and W(O) Fischer-type carbene complexes as ligands are described. The catalytic activity of the zirconocene W(O) carbene complex was tested as well. The second section of this study comprises a report on novel thiazolinylidene complexes of Mn(I), prepared via protonation or alkylation from thiazolyl complexes.
dc.description.abstractAFRIKAANSE OPSOMMING: In die eerste deel van hierdie verhandeling word die bereiding van anioniese Fischer-tipe wolfram(O)- en mangaan(I)karbeenkomplekse as ligande vir sirkoniumverbindings beskryf. Die aldus gevormde sirkonium-W(O)karbeenkompleks se katalitiese aktiwiteit is ondersoek. Die tweede deel bevat 'n beskrywing van nuwe tiasolinilideenkomplekse van Mn(I) wat via alkilering of protonering van tiasolielkomplekse berei is.
dc.description.versionMaster
dc.format.extent139 pages : ill.
dc.identifier.urihttp://hdl.handle.net/10019.1/70246
dc.language.isoaf_ZAaf_ZA
dc.publisherStellenbosch : Stellenbosch University
dc.rights.holderStellenbosch University
dc.subjectCarbon compoundsen_ZA
dc.subjectCarbenes (Methylene compounds)en_ZA
dc.subjectChemistry, Inorganicen_ZA
dc.subjectDissertations -- Chemistryen_ZA
dc.subjectZirconocene complexesen_ZA
dc.subjectThiazolinylidene complexesen_ZA
dc.titleMono- en dikernige karbeenkomplekse van Mn(I) en W(O)af_ZA
dc.typeThesisen_ZA
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