Bis[μ-1,2-bis-(diphenyl-phosphino)ethane-2 κ P:P′]digold(I)(Au - Au) bis-(trifluoro-methane-sulfonate) acetonitrile disolvate

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dc.contributor.authorStrasser C.E.
dc.contributor.authorCronje S.
dc.contributor.authorRaubenheimer H.G.
dc.date.accessioned2011-05-15T15:56:17Z
dc.date.available2011-05-15T15:56:17Z
dc.date.issued2009
dc.description.abstractThe title compound, [Au2(C26H24P 2)2](CF3SO3)2· 2CH3CN, comprises a cyclic cation with a short intra-molecular aurophilic inter-action of 2.9220 (3) Å. The trifluoro-methane-sulfonate anions and acetonitrile solvent mol-ecules are located in channels formed by the complex cations that run along the crystallographic c axis. Each counter-anion is also engaged in a C - H⋯O contact with one of the methyl-ene H atoms of a 1,2-bis-(diphenyl-phosphino)ethane (dppe) ligand; another C - H⋯O contact involving an aromatic H atom is also observed. © 2009 Strasser et al.
dc.description.versionArticle
dc.identifier.citationActa Crystallographica Section E: Structure Reports Online
dc.identifier.citation65
dc.identifier.citation8
dc.identifier.issn16005368
dc.identifier.other10.1107/S1600536809025513
dc.identifier.urihttp://hdl.handle.net/10019.1/9770
dc.subjectTrifluoro
dc.titleBis[μ-1,2-bis-(diphenyl-phosphino)ethane-2 κ P:P′]digold(I)(Au - Au) bis-(trifluoro-methane-sulfonate) acetonitrile disolvate
dc.typeArticle
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