Monomeric linear diaminocarbene complexes of gold(I) show merit in enantioselective catalysis

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dc.contributor.authorRaubenheimer H.G.
dc.date.accessioned2012-06-28T09:00:49Z
dc.date.available2012-06-28T09:00:49Z
dc.date.issued2012
dc.description.abstractStriking gold: Rather simple aryl substituents are required to convert acyclic diaminocarbenes (ADCs) into useful pseudo-bidentate ligands for monomeric gold(I), which can enantioselectively catalyze a tandem acetylization/cycloisomerization reaction. Tf=trifluoromethanesulfonyl. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
dc.identifier.citationAngewandte Chemie - International Edition
dc.identifier.citation51
dc.identifier.citation21
dc.identifier.citation5042
dc.identifier.citation5044
dc.identifier.issn14337851
dc.identifier.otherdoi:10.1002/anie.201200739
dc.identifier.urihttp://hdl.handle.net/10019.1/21476
dc.subjectAcyclic diaminocarbenes
dc.subjectAryl substituents
dc.subjectCyclizations
dc.subjectEnantioselective catalysis
dc.subjectHomogeneous catalysis
dc.subjectLigand design
dc.subjectEnantioselectivity
dc.subjectGold
dc.subjectLigands
dc.subjectReaction kinetics
dc.subjectSubstitution reactions
dc.subjectGold compounds
dc.titleMonomeric linear diaminocarbene complexes of gold(I) show merit in enantioselective catalysis
dc.typeArticle
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