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Bis(1,3-benzothia-zol-2-amine-N 3)silver(I) nitrate acetone solvate

Strasser C.E. ; De Jongh L.-A. ; Cronje S. ; Raubenheimer H.G. (2009)


In the title compound, [Ag(C7H6N2S) 2]NO3·C3H6O, the AgI ion is coordinated to two benzothia-zol-2-amine ligands via the thia-zole N atoms in an approximately linear arrangement. The dihedral angle between the mean planes of the two 1,3-benzothia-zole groups is 5.9 (3)°. Both amine groups on the ligands are oriented in the same direction and are engaged in N - H⋯O hydrogen bonding with the nitrate counter-anion, forming one-dimensional columns along the b-axis direction. Voids created by inefficient crystal packing are occupied by acetone solvent mol-ecules which are disordered over two sites with occupancies of 0.563 (11) and 0.437 (11).

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