[(3-Methylphenyl)(triphenylphosphonio)-methanide-κC] triphenylphosphorane}-(pentafluorophenyl-κC)gold(I) diethyl ether solvate

Strasser C.E. ; Coetzee K. ; Cronje S. ; Raubenheimer H.G. (2009)


The metal atom in the title ylid-gold(I) adduct, [Au(C6F 5)(C26H23P)]·C4H 10O, exists in a linear coordination environment [C- Au- C = 174.1 (2)°]. The mol-ecule has a short intra-molecular contact involving an aromatic H atom (Au⋯H = 2.64 Å); two adjacent mol-ecules are linked by an Au⋯Hylid inter-action (Au⋯H = 3.14 Å).

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