Masters Degrees (Centre for Renewable and Sustainable Energy Studies)
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This collection contains dissertations sponsored by the Centre for Renewable and Sustainable Energy Studies.
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Browsing Masters Degrees (Centre for Renewable and Sustainable Energy Studies) by Subject "Biomass energy"
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- ItemBiodiesel analytical development and characterisation.(Stellenbosch : University of Stellenbosch, 2010-03) Prah, Ebenezer; Callanan, L. H.; Lorenzen, L.; University of Stellenbosch. Faculty of Engineering. Dept. of Process Engineering.ENGLISH ABSTRACT: Development of analytical methods to characterise biodiesel has become central to the overall success of the marketing of biodiesel fuel. In this regard, different bodies including the American Society for Testing and Materials (ASTM) and the European normalization (EN) have come up with various methods to determine important biodiesel parameters such as total glycerol, methanol and the fatty acid methyl esters (FAMEs), etc. Various studies have been conducted on the parameters mentioned above using a variety of instrumentation and sample preparations. The best methods reported are those that have been adopted by both the ASTM and EN standards. The purpose of this study was to develop alternative analytical methods to both the recommended ASTM and EN methods and, in some cases, to make modifications to both standards (ASTM D 6571 and EN 14214) and methods to determine total and bound glycerol, the ester content and also methanol content in biodiesel. Moreover, water washing after transesterification and the effect this practice has on biodiesel cold flow properties such as kinematic viscosity, cloud and pour point and density were evaluated. The possibility of using the iodine value to predict the feedstock source of an unknown biodiesel was also investigated. Six different vegetable oil samples were transesterified with methanol and used for this study. The six samples used were palm, crown, sunflower, waste vegetable oil (wvo), peanut and rapeseed biodiesel. Quantitative results indicated that the use of programmable temperature volatilisation (PTV) for total glycerol did not produce the required repeatability of between 1-4% relative standard deviation(RSD) for total glycerol analyses in biodiesel with precision of 25%, 86%, 25% and 56% for free glycerol (FG), monoglycerides (MG), diglycerides (DG), and triglycerides (TG) respectively. The standard requires a relative standard of between 1-4% As an alternative to the method using gas chromatography, normal phase high performance chromatography (HPLC) with binary gradient elution was used to determine the bound glycerol content. This method proved accurate and repeatable with RSD % of 0.33, 1.12, and 1.2 for TG, DG and MG respectively. Following the EN14103 protocol (European standard ester determination), the Zebron ZBWAX column which is comparable to the specification recommended by EN14103 but afforded the determination of ester content from the esters of myristic acid (C14:0) to behenic acid (C22:0) with reproducibility with RSD % of 6.81, 1.91, 7.27, 0.64, 1.18, 1.55, 6.03, 1.96, and 5.21 for methyl esters of myristic, palmitic, stearic, oleic, linoleic, linolenic, arachidoic, gadoleic and behenic acid respectively. Solid phase micro extraction (SPME) using GC-MS was developed as an alternative to both the EN14110 and ASTM D93 protocols for determining the methanol content in biodiesel. For this method, polyethylene glycol fibre (PEG) was used together with a deuterated methanol internal standard and a DB-FFAP (60m×0.25um×0.25um) column. Less volume of sample was required as compared to the EN14214 method. This method was found to be sensitive, accurate and repeatable with a RSD % of 4.82. The Iodine number of biodiesel decrease compared to their corresponding feed stock and therefore predicting the feed stock of an unknown biodiesel was going to be difficult .Results from this study indicated that it is not possible to predict the feed stock source of an unknown biodiesel from its iodine value. The effect of water washing after phase separation on biodiesel cold flow properties such as kinematic viscosity, density, cloud and pour point depended on the type of biodiesel produced. We observed that water washing after transesterification caused an increase in all the cold flow properties of sunflower biodiesel, whereas only the densities and kinematic viscosities increased in the case of palm and waste vegetable oil biodiesel. The cloud and pour point of the latter two diesel samples remained unchanged after water washing. Thus, the effect of water washing on biodiesel cold flow depended on the type of biodiesel. Blending a highly saturated biodiesel (fewer numbers of double bonds) with a less saturated biodiesel (higher number of double bonds) resulted in an improvement of both the pour and cloud points of the resultant biodiesel blend.
- ItemCarbon finance and reforestation : a survey of African cases(Stellenbosch : University of Stellenbosch, 2010-12) Lagrange, Chantal V. M.; Stamm, A.; McDonald, I. A. W.; University of Stellenbosch. Faculty of Economic and Management Sciences. School of Public Leadership.ENGLISH ABSTRACT: This thesis addresses the topic of carbon finance in the context of reforestation and avoided deforestation. The research is based on the Nhambita Reduced Emissions from Deforestation and Degradation (REDD) and Agro-forestry carbon offset project in North West Mozambique. The thesis raises important questions in terms of the relevance of carbon offset projects to human and biophysical realities in Africa. The research was conducted through the lens of ethnographic development and explores how carbon offset projects are received by recipient communities. What issues do such projects attempt to address? Are the targeted issues the „real‟ issues, as they are perceived by local populations in developing countries? Who do such projects benefit and who do they benefit the most? The thesis comprises two academic papers. The first paper is a synthesis article presenting a review of key issues with regards to the roll-out of improved cooking stoves (ICS) in the context of carbon offset projects, combined with a pre-feasibility study on the introduction of ICS in the Nhambita village. It shows how biomass will continue to play a dominant role in addressing Southern African energy needs and how a large scale dissemination of ICS could play a seminal role in alleviating pressure on threatened ecosystems. The paper, however, recognizes that ICS programmes are not a panacea and discusses the pitfalls of paradigms underlying stove-provision programmes to date. Based on a review of the pertinent literature and on the field work conducted in Mozambique, conclusions are drawn that environmental and health considerations do not constitute a sufficient „pull‟ factor from the end user‟s perspective. It appears that best channels to engage with the targeted users are economic and social rationales. This debate is of particular relevance to climate change policy but it also offers insights in terms of the acceptance of such programmes by the target communities. The second paper is related to the first in that it discusses the opportunities and challenges associated with the developmental ambitions of carbon offset projects. By virtue of the market systems that regulate them, such carbon offset projects imply an innovative developmental praxis, whereby project recipients become the owners and the sellers of a tangible good in the form of carbon credits. This innovative dimension is, however, thwarted by the fact that such projects stir welfare expectations from project participants. Such livelihood improvement expectations become the fertile ground for difficulties reminiscent of the weakness of traditional aid. The intricacies underpinning this new mechanism that combines land use changes with environmental conservation and livelihood benefits are debated in the context of private entrepreneurship and global markets. The analysis is anchored in a socioanthropological interpretation of climate change science and lays the emphasis on the risks and constraints of such projects, from the perspective of the target communities. The paper concludes by discussing the policy implications of these findings.
- ItemThe development of a biofuels engine testing facility(Stellenbosch : Stellenbosch University, 2008-12) Palmer, Duncan; Lorenzen, L.; Van der Spuy, Johan; Stellenbosch University. Faculty of Engineering. Dept. of Process Engineering.; Stellenbosch University. Faculty of Engineering. Dept. of Mechanical and Mechatronic Engineering.This report covers the development of a biofuels engine testing facility at Stellenbosch University. The motivation for the project was three fold: a) a desire to establish biofuels and engine testing know-how; b) to test the performance characteristics of biodiesel; and c) make a facility available for future research. The two main conclusions drawn from the initial test results are: 1) the test cell is fully operational and 2) biodiesel can be substituted for mineral diesel. To the author’s knowledge this is the first biofuel specific engine testing facility in South Africa. After a literature study the test cell was realised in three phases. • Firstly, the hardware layout was designed and the necessary equipment was sourced from respectable suppliers including the judicious use of good qaulity second hand components to minimize capital cost. • The test cell was then instrumented with new sensors. Key components among these are the K-type thermocouples, barometric pressure, humidity, oil pressure and an Allen-Bradley programmable controller to serve as a data acquisition card. Two software programs were chosen, ETA for the control of the test cell and RSLogix to program the programmable logic controller (PLC). • The complete system was then integrated, debugged and validated. The design methods and procedures have been documented throughout the project along with user manuals to facilitate further research. To determine the difference in combustion parameters between biodiesel and mineral diesel an autonomous power curve test was conducted. This revealed little difference in terms of performance between the two fuels, although biodiesel had on average a marginal 0.4% decrease in power over mineral diesel. The fuel consumption for pure biodiesel was found to be higher, which is as expected as it is has a lower calorific value than mineral diesel. As a final validation, an energy balance was conducted. Here the calculated calorific value of biodiesel was compared to the results from a calorie bomb test, and the two results were found to be within 2% of each of other.
- ItemEvaluation of different process designs for biobutanol production from sugarcane molasses(Stellenbosch : Stellenbosch University, 2010-03) Van der Merwe, Abraham Blignault; Knoetze, J. H.; Gorgens, Johann F.; Stellenbosch University. Faculty of Engineering. Dept. of Process Engineering.ENGLISH ABSTRACT: Recently, improved technologies have been developed for the biobutanol fermentation process: higher butanol concentrations and productivities are achieved during fermentation, and separation and purification techniques are less energy intensive. This may result in an economically viable process when compared to the petrochemical pathway for butanol production. The objective of this study is to develop process models to compare different possible process designs for biobutanol production from sugarcane molasses. Some of the best improved strains, which include Clostridium acetobutylicum PCSIR-10 and Clostridium beijerinckii BA101, produce total solvent concentrations of up to 24 g/L. Among the novel technologies for fermentation and downstream processing, fedbatch fermentation with in situ product recovery by gas-stripping, followed by either liquid-liquid extraction or adsorption, appears to be the most promising techniques for current industrial application. Incorporating these technologies into a biorefinery concept will contribute toward the development of an economically viable process. In this study three process routes are developed. The first two process routes incorporate well established industrial technologies: Process Route 1 consist of batch fermentation and steam stripping distillation, while in Process Route 2, some of the distillation columns is replaced with a liquid-liquid extraction column. The third process route incorporates fed-batch fermentation and gas-stripping, an unproven technology on industrial scale. Process modelling in ASPEN PLUS® and economic analyses in ASPEN Icarus® are performed to determine the economic feasibility of these biobutanol production process designs. Process Route 3 proved to be the only profitable design in current economic conditions. For the latter process, the first order estimate of the total project capital cost is $187 345 000.00 (IRR: 35.96%). Improved fermentation strains currently available are not sufficient to attain a profitable process design without implementation of advanced processing techniques. Gas stripping is shown to be the single most effective process step (of those evaluated in this study) which can be employed on an industrial scale to improve process economics of biobutanol production.
- ItemPyrolysis of sugarcane bagasse(Stellenbosch : University of Stellenbosch, 2010-12) Hugo, Thomas Johannes; Knoetze, J. H.; Gorgens, Johann F.; University of Stellenbosch. Faculty of Engineering. Dept. of Process Engineering.ENGLISH ABSTRACT: The world’s depleting fossil fuels and increasing greenhouse gas emissions have given rise to much research into renewable and cleaner energy. Biomass is unique in providing the only renewable source of fixed carbon. Agricultural residues such as Sugarcane Bagasse (SB) are feedstocks for ‘second generation fuels’ which means they do not compete with production of food crops. In South Africa approximately 6 million tons of raw SB is produced annually, most of which is combusted onsite for steam generation. In light of the current interest in bio-fuels and the poor utilization of SB as energy product in the sugar industry, alternative energy recovery processes should be investigated. This study looks into the thermochemical upgrading of SB by means of pyrolysis. Biomass pyrolysis is defined as the thermo-chemical decomposition of organic materials in the absence of oxygen or other reactants. Slow Pyrolysis (SP), Vacuum Pyrolysis (VP), and Fast Pyrolysis (FP) are studied in this thesis. Varying amounts of char and bio-oil are produced by the different processes, which both provide advantages to the sugar industry. Char can be combusted or gasified as an energy-dense fuel, used as bio-char fertilizer, or upgraded to activated carbon. High quality bio-oil can be combusted or gasified as a liquid energy-dense fuel, can be used as a chemical feedstock, and shows potential for upgrading to transport fuel quality. FP is the most modern of the pyrolysis technologies and is focused on oil production. In order to investigate this process a 1 kg/h FP unit was designed, constructed and commissioned. The new unit was tested and compared to two different FP processes at Forschungszentrum Karlsruhe (FZK) in Germany. As a means of investigating the devolatilization behaviour of SB a Thermogravimetric Analysis (TGA) study was conducted. To investigate the quality of products that can be obtained an experimental study was done on SP, VP, and FP. Three distinct mass loss stages were identified from TGA. The first stage, 25 to 110°C, is due to evaporation of moisture. Pyrolitic devolatilization was shown to start at 230°C. The final stage occurs at temperatures above 370°C and is associated with the cracking of heavier bonds and char formation. The optimal decomposition temperatures for hemicellulose and cellulose were identified as 290°C and 345°C, respectively. Lignin was found to decompose over the entire temperature range without a distinct peak. These results were confirmed by a previous study on TGA of bagasse. SP and VP of bagasse were studied in the same reactor to allow for accurate comparison. Both these processes were conducted at low heating rates (20°C/min) and were therefore focused on char production. Slow pyrolysis produced the highest char yield, and char calorific value. Vacuum pyrolysis produced the highest BET surface area chars (>300 m2/g) and bio-oil that contained significantly less water compared to SP bio-oil. The short vapour residence time in the VP process improved the quality of liquids. The mechanism for pore formation is improved at low pressure, thereby producing higher surface area chars. A trade-off exists between the yield of char and the quality thereof. FP at Stellenbosch University produced liquid yields up to 65 ± 3 wt% at the established optimal temperature of 500°C. The properties of the bio-oil from the newly designed unit compared well to bio-oil from the units at FZK. The char properties showed some variation for the different FP processes. At the optimal FP conditions 20 wt% extra bio-oil is produced compared to SP and VP. The FP bio-oil contained 20 wt% water and the calorific value was estimated at 18 ± 1 MJ/kg. The energy per volume of FP bio-oil was estimated to be at least 11 times more than dry SB. FP was found to be the most effective process for producing a single product with over 60% of the original biomass energy. The optimal productions of either high quality bio-oil or high surface area char were found to be application dependent.