Attempted synthesis of a meta-metalated calix[4]arene

Simple item page
dc.contributor.authorJurisch, Christopher D.en_ZA
dc.contributor.authorArnott, Gareth E.en_ZA
dc.date.accessioned2021-11-10T11:44:50Z
dc.date.available2021-11-10T11:44:50Z
dc.date.issued2019
dc.descriptionCITATION: Jurisch, C. D. & Arnott, G. E. 2019. Attempted synthesis of a meta-metalated calix[4]arene. Beilstein Journal of Organic Chemistry, 15:1996-2002, doi:10.3762/bjoc.15.195.
dc.descriptionThe original publication is available at https://www.beilstein-journals.org/bjoc
dc.description.abstractENGLISH ABSTRACT: An evidence for the formation of a rare meta-metalated inherently chiral calix[4]arene is described. Our strategy involved using a mesoionic carbene to direct C–H activation, but proved to form an unexpectedly unstable intermediate that was identified through high-resolution mass spectrometry. On route to our target, a new optimized method to mononitrocalix[4]arenes was developed, including optimized and high yielding transformations to azide and 1,2,3-triazole derivatives which may have application in other areas of research.en_ZA
dc.description.urihttps://www.beilstein-journals.org/bjoc/articles/15/195
dc.description.versionPublisher's version
dc.format.extent7 pagesen_ZA
dc.identifier.citationJurisch, C. D. & Arnott, G. E. 2019. Attempted synthesis of a meta-metalated calix[4]arene. Beilstein Journal of Organic Chemistry, 15:1996-2002, doi:10.3762/bjoc.15.195
dc.identifier.issn1860-5397 (online)
dc.identifier.otherdoi:10.3762/bjoc.15.195
dc.identifier.urihttp://hdl.handle.net/10019.1/123416
dc.language.isoen_ZAen_ZA
dc.publisherBeilstein-Instituten_ZA
dc.rights.holderAuthors retain copyrighten_ZA
dc.subjectCalixarenesen_ZA
dc.subjectMacrocyclic compoundsen_ZA
dc.subjectFormaldehydeen_ZA
dc.titleAttempted synthesis of a meta-metalated calix[4]areneen_ZA
dc.typeArticleen_ZA
Files
Original bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
jurisch_attempted_2019.pdf
Size:
1.71 MB
Format:
Adobe Portable Document Format
Description:
Download article
Download
License bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
license.txt
Size:
1.71 KB
Format:
Item-specific license agreed upon to submission
Description:
Download
Collections
Research Articles (Chemistry and Polymer Science)