Masters Degrees (Electrical and Electronic Engineering)
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Browsing Masters Degrees (Electrical and Electronic Engineering) by browse.metadata.advisor "Aldrich, C."
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- ItemThe development of a one-dimensional quasi-steady state model for the desulphurisation process at Saldanha Steel(Stellenbosch : University of Stellenbosch, 2003-04) Scheepers, Emile; Eksteen, J. J.; Aldrich, C.; University of Stellenbosch. Faculty of Engineering. Dept. of Process Engineering.ENGLISH ABSTRACT: The pneumatic injection of reagent powder into molten iron has become the preferred way to carry out iron and steel desulphurisation. It is therefore essential to not only understand the thermodynamic implications, but also the kinetic principles that govern the desulphurisation process. Key variables that influence the kinetics of the procedure are the condition and composition of the top slag and the melt as well as the injection conditions. Notable injection parameters include reagent flowrate, injection-lance depth and carrier gas flowrate. Owing to sampling restrictions, the subsequent data from Saldanha Steel®, South Africa does not provide adequate insight into the kinetic behaviour of the desulphurisation process and it was therefore the focus of this research to provide an improved quantitive comprehension of the calcium carbide injection procedure at Saldanha Steel. For this purpose a one-dimensional quasi-steady state model for momentum, heat- and mass transfer in rising gas-liquid-powder plumes has been developed for conditions relevant to the Saldanha Steel refining process. Combined with a model predicting the contribution of the topslag to the process, the overall rate of desulphurisation as a function of time can be determined, thus affording the ability to quantitatively explore and analyse the influence of the afore-mentioned injection parameters, as well as the nature of both the topslag and the melt, on the kinetics of the desulphurisation process. Sensitivity analyses concluded that individual increases in the calcium carbide flowrate, the depth of injection and the amount of carry-over slag will result in a reduction in the injection time, while a decrease in the reagent particle diameter and the initial mass of iron in the ladle will have the same effect. Molten iron temperature losses brought about by prolonged injection needs to be electrically recovered within a steelmaking furnace at a high cost. Owing to the high cost of the desulphurising agent, any reduction in the required injection time, while still maintaining product specifications, will therefore result in diminishing overall production costs. Although all the results contained in this study is of particular interest to the Saldanha Steel scenario, it also provides invaluable information and insights into the important variables and parameters playing a role in injection desulphurisation processes in general, along with the influence that changing conditions can have on the end result of such a procedure.