Penta-carbonyl-2κ5 C-chlorido-1κCl-bis- [1(η5)-cyclo-penta-dien-yl][μ-oxido(phenyl)methylene-1: 2κ2 O:C]hafnium(IV)tungsten(0)

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dc.contributor.authorEsterhuysen C.
dc.contributor.authorNel I.B.J.
dc.contributor.authorCronje S.
dc.date.accessioned2011-05-15T15:56:19Z
dc.date.available2011-05-15T15:56:19Z
dc.date.issued2008
dc.description.abstractThe title compound, [HfW(C5H5)2(C7H5O)Cl(CO)5] or [W(CO)5(C7H5O){Hf(C5H5) 2Cl}], contains two metal centres, with a (tungstenpenta-carbon-yl)oxy-phenyl- carbene unit coordinated to a hafnocene chloride. The Hf - O - C angle is nearly linear, and the C=O distance is slightly shorter than for equivalent alkoxy-carbenes. One of the cyclo-penta-dienyl (Cp) rings undergoes an offset face-to-face π-π inter-action [3.495 (7) Å] with the symmetry-related Cp ring of a neighbouring mol-ecule.
dc.description.versionArticle
dc.identifier.citationActa Crystallographica Section E: Structure Reports Online
dc.identifier.citation64
dc.identifier.citation9
dc.identifier.issn16005368
dc.identifier.other10.1107/S1600536808025245
dc.identifier.urihttp://hdl.handle.net/10019.1/9780
dc.titlePenta-carbonyl-2κ5 C-chlorido-1κCl-bis- [1(η5)-cyclo-penta-dien-yl][μ-oxido(phenyl)methylene-1: 2κ2 O:C]hafnium(IV)tungsten(0)
dc.typeArticle
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