Penta-carbonyl-2 κ5C-chlorido-1κCl-bis- [1(η5)-cyclo-penta-dien-yl][2-oxido(meth-yl)methyl- ene-1:22 O:C]tungsten(0)zirconium(IV)

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dc.contributor.authorEsterhuysen C.
dc.contributor.authorNeveling A.
dc.contributor.authorLuruli N.
dc.contributor.authorKruger G.J.
dc.contributor.authorCronje S.
dc.date.accessioned2011-05-15T15:56:19Z
dc.date.available2011-05-15T15:56:19Z
dc.date.issued2008
dc.description.abstractThe title compound, [ZrW(C5H5)2(C2H3O)Cl(CO)5] or [W(CO)5C(CH3)OZr(C5H5) 2Cl], consists of two metal centres, with a (tungsten penta-carbon-yl)oxymethyl- carbene group coordinating as a monodentate ligand to the chloridozirconocene. The two halves of the mol-ecule are related by a crystallographic mirror plane. Delocalization through the Zr - O - C=W unit is indicated by a short Zr - O distance and a nearly linear Zr - O - C angle.
dc.description.versionArticle
dc.identifier.citationActa Crystallographica Section E: Structure Reports Online
dc.identifier.citation64
dc.identifier.citation10
dc.identifier.issn16005368
dc.identifier.other10.1107/S1600536808028006
dc.identifier.urihttp://hdl.handle.net/10019.1/9779
dc.titlePenta-carbonyl-2 κ5C-chlorido-1κCl-bis- [1(η5)-cyclo-penta-dien-yl][2-oxido(meth-yl)methyl- ene-1:22 O:C]tungsten(0)zirconium(IV)
dc.typeArticle
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