Penta-carbonyl-25 C-chlorido-1Cl-bis-[1(5)-cyclo- penta-dien-yl]( - Oxido-benzyl-idene-1:2κ2 O:C)titanium(IV) tungsten(0)

Esterhuysen C. ; Nel I.B.J. ; Esterhuysen M.W. ; Cronje S. (2008)


The title compound, [TiW(C5H5)2(C7H5O)Cl(CO)5], consists of two metal centres, with a (tungstenpenta-carbon-yl)oxy-phenyl-carbene unit coordinated by a titanocene chloride. The oxycarbene group is nearly planar, with the phenyl ring twisted by an angle of 39.1 (2)° with respect to this plane. One of the cyclo-penta-dienyl rings undergoes an offset face-to-face π-π inter-action [3.544 (6) Å] with the symmetry-related cyclo-penta-dienyl ring of a neighbouring mol-ecule. © 2008.

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