Monomeric linear diaminocarbene complexes of gold(I) show merit in enantioselective catalysis
Date
2012
Authors
Raubenheimer H.G.
Journal Title
Journal ISSN
Volume Title
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Abstract
Striking gold: Rather simple aryl substituents are required to convert acyclic diaminocarbenes (ADCs) into useful pseudo-bidentate ligands for monomeric gold(I), which can enantioselectively catalyze a tandem acetylization/cycloisomerization reaction. Tf=trifluoromethanesulfonyl. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Description
Keywords
Acyclic diaminocarbenes, Aryl substituents, Cyclizations, Enantioselective catalysis, Homogeneous catalysis, Ligand design, Enantioselectivity, Gold, Ligands, Reaction kinetics, Substitution reactions, Gold compounds
Citation
Angewandte Chemie - International Edition
51
21
5042
5044
51
21
5042
5044