Monomeric linear diaminocarbene complexes of gold(I) show merit in enantioselective catalysis

Raubenheimer H.G. (2012)


Striking gold: Rather simple aryl substituents are required to convert acyclic diaminocarbenes (ADCs) into useful pseudo-bidentate ligands for monomeric gold(I), which can enantioselectively catalyze a tandem acetylization/cycloisomerization reaction. Tf=trifluoromethanesulfonyl. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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