In situ X-ray structural studies of a flexible host responding to incremental gas loading

Jacobs T. ; Lloyd G.O. ; Gertenbach J.-A. ; Muller-Nedebock K.K. ; Esterhuysen C. ; Barbour L.J. (2012)


Crystallographic pressure-lapse snapshots of a porous material responding to gas loading were used to investigate the stepwise uptake of carbon dioxide and acetylene molecules into discrete confined spaces. Based on the data, a qualitative statistical mechanical model was devised that reproduces even subtle features in the experimental gas sorption isotherms. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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