In situ X-ray structural studies of a flexible host responding to incremental gas loading
Date
2012
Authors
Jacobs T.
Lloyd G.O.
Gertenbach J.-A.
Muller-Nedebock K.K.
Esterhuysen C.
Barbour L.J.
Journal Title
Journal ISSN
Volume Title
Publisher
Abstract
Crystallographic pressure-lapse snapshots of a porous material responding to gas loading were used to investigate the stepwise uptake of carbon dioxide and acetylene molecules into discrete confined spaces. Based on the data, a qualitative statistical mechanical model was devised that reproduces even subtle features in the experimental gas sorption isotherms. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Description
Keywords
acetylene, carbon dioxide, flexible pores, gas sorption, inclusion compounds
Citation
Angewandte Chemie - International Edition
51
20
4913
4916
51
20
4913
4916