Inclusion of thiazyl radicals in porous crystalline materials
Date
2011
Authors
Potts S.V.
Barbour L.J.
Haynes D.A.
Rawson J.M.
Lloyd G.O.
Journal Title
Journal ISSN
Volume Title
Publisher
Abstract
The incorporation of benzodithiazolyl (BDTA) and methylbenzodithiazolyl (MBDTA) radicals into porous hybrid frameworks via gas phase diffusion revealed that inclusion appeared selective for the MIL53(Al) framework against a range of other potential hosts. Both PXRD and EPR studies are consistent with retention of a π*-π* dimer motif for BDTA in MIL53(Al)@BDTA whereas MBDTA in MIL53(Al)@MBDTA appears to be monomeric. The guests are readily released by the addition of solvent (CH2Cl2). © 2011 American Chemical Society.
Description
Keywords
Dimer motifs, EPR studies, Gas phase diffusion, Hybrid framework, Aluminum, Crystalline materials, Dimers, Hybrid materials, benzodithiazolyl, methylbenzodithiazolyl, radical, thiazole derivative, unclassified drug, article, chemical structure, conformation, crystallization, diffusion, electron spin resonance, gas, room temperature, synthesis, ultraviolet radiation
Citation
Journal of the American Chemical Society
133
33
http://www.scopus.com/inward/record.url?eid=2-s2.0-80051709990&partnerID=40&md5=77734685bffa89e930d59ce2a4166a85
133
33
http://www.scopus.com/inward/record.url?eid=2-s2.0-80051709990&partnerID=40&md5=77734685bffa89e930d59ce2a4166a85