New self-assembled one-dimensional nickel coordination polymers and hydrogen-bonded networks

Vujovic D. ; Raubenheimer H.G. ; Nassimbeni L.R. (2003)


Reaction of Ni(NCS)2 with aminobenzonitrile (ABN) isomers in solution gave rise to the formation of five coordination polymers of the general formula [Ni(NCS)2(ABN)2]n consisting of one-dimensional chains with adjacent nickel centres linked by bridging NCS- or ABN ligands. The compounds were characterised by single crystal X-ray diffraction, X-ray powder diffraction, infrared spectroscopy, thermogravimetry, differential scanning calorimetry and mass spectrometry.

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