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Microscopic surface and bulk morphology of semicrystalline poly(dimethylsiloxane)-polyester copolymers

dc.contributor.authorAbduallah, A. B. E.
dc.contributor.authorMallon, P. E.
dc.date.accessioned2011-05-15T15:59:26Z
dc.date.available2011-05-15T15:59:26Z
dc.date.issued2010
dc.identifier.citationJournal of Applied Polymer Science
dc.identifier.citation115
dc.identifier.citation3
dc.identifier.issn218995
dc.identifier.other10.1002/app.31103
dc.identifier.urihttp://hdl.handle.net/10019.1/11174
dc.description.abstractIn this study, two series of semicrystalline poly(dimethylsiloxane) (PDMS)-polyester segmented copolymers with various PDMS contents were synthesized. One series was based on polybutylene adipate (PBA) as the polyester segment and the other was based on a polybutylene cyclohexanedicarboxylate ester (PBCH) segment. The copolymers were characterized using 1H-nuclear magnetic resonance, size exclusion chromatography, dynamic mechanical analyses, differential scanning calorimetry (DSC), and wide-angle X-ray diffraction (WAXD). The microscopic surface morphology and the microscopic bulk morphology were investigated using atomic force microscopy (AFM) and transmission electron microscopy, respectively. The effects of the polyester type and the PDMS content on the crystallinity degree as well as the copolymer surface and bulk morphology at room temperature were investigated for each series. DSC and WAXD results showed the ability of the copolymers to crystallize, to various degrees, depending on the polyester type and the PDMS content. The results showed that the PDMS content had a greater influence on the crystallinity degree in the PDMS-s-PBCH (cycloaliphatic) copolymer series than in the PDMS-s-PBA (aliphatic) copolymer series. In the copolymers with a low PDMS content, the AFM images showed spherulitic crystal morphology and evidence of PDMS nanodomains in between the crystal lamellae of the ester phase on the copolymer surface. A heterogeneous distribution of the PDMS domains was also observed for these copolymers in the bulk morphology as a result of this segregation between the polyester lamellae. All the copolymers, in both series, showed microphase separation as a result of the incompatibility between the PDMS segment and the polyester segment. Three types of surfaces and bulk morphologies were observed: spherical microdomains of PDMS in a matrix of polyester, bicontinuous double-diamond type morphology, and spherical microdomains of polyester in a matrix of PDMS as the PDMS content increases. © 2009 Wiley Periodicals, Inc.
dc.subjectAFM
dc.subjectPoly(dimethylsiloxane)-polyester copolymer
dc.subjectSegmented copolymer
dc.subjectSegmented copolymer morphology
dc.subjectTEM
dc.subjectAtomic force microscopy
dc.subjectChromatographic analysis
dc.subjectCopolymerization
dc.subjectCopolymers
dc.subjectDifferential scanning calorimetry
dc.subjectEsterification
dc.subjectEsters
dc.subjectMicrochannels
dc.subjectMicrophase separation
dc.subjectMorphology
dc.subjectNuclear magnetic resonance spectroscopy
dc.subjectOrganic polymers
dc.subjectPacket networks
dc.subjectPlastic products
dc.subjectResonance
dc.subjectSeparation
dc.subjectSilicones
dc.subjectSize exclusion chromatography
dc.subjectTransmission electron microscopy
dc.subjectX ray diffraction analysis
dc.subjectSurface morphology
dc.subjectcopolymer
dc.subjectcrystallinity
dc.subjectphase separation
dc.subjectpolybutylene
dc.subjectpolydimethylsiloxane
dc.subjectpolyester
dc.subjectsynthesis
dc.subjecttemperature effect
dc.titleMicroscopic surface and bulk morphology of semicrystalline poly(dimethylsiloxane)-polyester copolymers
dc.typeArticle
dc.description.versionArticle


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