Imine-donor complexes with group 6 and group 11 transition metals : coordination and dynamics

Simple item page
dc.contributor.advisorCronje, S.en_ZA
dc.contributor.advisorRaubenheimer, H. G.en_ZA
dc.contributor.authorDe Jongh, Leigh-Anneen_ZA
dc.contributor.otherStellenbosch University. Faculty of Science. Dept. of Chemistry and Polymer Science.
dc.date.accessioned2008-09-16T08:24:11Zen_ZA
dc.date.accessioned2010-06-01T08:38:32Z
dc.date.available2008-09-16T08:24:11Zen_ZA
dc.date.available2010-06-01T08:38:32Z
dc.date.issued2008-12en_ZA
dc.descriptionThesis (MSc (Chemistry and Polymer Science))--Stellenbosch University, 2008.en_ZA
dc.description.abstractIn this study the coordination of ligands with several coordination sites, 2-aminoazoles (2- amino-4-methylthiazole), 2-aminobenzothiazole, 2-aminobenzoimidazole and 2- aminothiazoline and a biguanidine (N-(2-methylphenyl)imidodicarbonimidic diamide) to soft metal centres [gold(I) (group 11), chromium(0) (group 6) and tungsten (0) (group 6)] was investigated. The aminoazoles have three coordination sites, an exocyclic amine nitrogen, an endocyclic imine nitrogen and an endocyclic thioether sulphur. The biguanidine ligand has three sites for deprotonation, one central amine and two imine nitrogens, and at least five sites available for nitrogen coordination.en_ZA
dc.identifier.urihttp://hdl.handle.net/10019.1/2001
dc.language.isoen_ZAen_ZA
dc.publisherStellenbosch : Stellenbosch University
dc.rights.holderStellenbosch University
dc.subjectImine coordinationen_ZA
dc.subjectGold complexesen_ZA
dc.subjectChromiumen_ZA
dc.subjectTungstenen_ZA
dc.subjectDissertations -- Chemistryen_ZA
dc.subjectTheses -- Chemistryen_ZA
dc.subjectCoordination compoundsen_ZA
dc.subjectLigandsen_ZA
dc.subject.otherChemistry and Polymer Scienceen_ZA
dc.titleImine-donor complexes with group 6 and group 11 transition metals : coordination and dynamicsen_ZA
dc.typeThesisen_ZA
Files
Original bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
dejongh_imine_2008.pdf
Size:
30.7 MB
Format:
Adobe Portable Document Format
Description:
Download
Collections
Masters Degrees (Chemistry and Polymer Science)