Hexakis(1H-imidazole-N 3)cobalt(III) tris-(hexa- fluoridophosphate) hexa-hydrate

Simple item page
dc.contributor.authorSurdykowski A.
dc.contributor.authorCzkowska A.
dc.contributor.authorDobrzaska L.
dc.contributor.authorSzyk E.
dc.date.accessioned2011-05-15T15:56:17Z
dc.date.available2011-05-15T15:56:17Z
dc.date.issued2009
dc.description.abstractIn the crystal structure of the title compound, [Co(C3H 4N2)6](PF6)3·6H2O, the CoIII atom lies on a special position with site-symmetry and the P atom is located on a special position with site symmetry . The CoIII atom has an almost ideal octa-hedral coordination formed by the N atoms of six imidazole ligands. The water mol-ecules form hydrogen-bonded helical chains propagating in [001] by O- H⋯O inter-actions with a distance of 2.913 (2) Å. They simultaneously inter-act as hydrogen-bond acceptors and donors with the cations and anions, respectively, resulting in the formation of a three-dimensional assembly. Weak C- H⋯F inter-actions further stabilize the crystal structure.
dc.description.versionArticle
dc.identifier.citationActa Crystallographica Section E: Structure Reports Online
dc.identifier.citation65
dc.identifier.citation10
dc.identifier.issn16005368
dc.identifier.other10.1107/S160053680903863X
dc.identifier.urihttp://hdl.handle.net/10019.1/9769
dc.titleHexakis(1H-imidazole-N 3)cobalt(III) tris-(hexa- fluoridophosphate) hexa-hydrate
dc.typeArticle
Files
Collections
Stellenbosch University - Scopus Publications