Mono- and bi-dentate Group 6-coordinated and titanium-containing isocyanide ligands prepared from benzoxazole

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dc.contributor.authorAn J.
dc.contributor.authorVan Niekerk L.
dc.contributor.authorEsterhuysen C.
dc.contributor.authorRaubenheimer H.G.
dc.date.accessioned2011-05-15T16:05:08Z
dc.date.available2011-05-15T16:05:08Z
dc.date.issued2002
dc.description.abstractReaction of lithiated benzoxazole with Group 6 carbonyl complexes and subsequently with Cp2TiCl2 affords bimetallic systems in which the titanium is O-bonded and the Group 6 metal isocyanide-coordinated. Depending on starting material and reaction conditions the cyclopentadienyl titanium complex may act as either a mono- or bi-dentate ligand. Crystal and molecular structures of [(CO)5Cr{CN(C6H4-o)O}Ti(Cl)Cp2] (1) and [(CO)4Cr-{CN(C6H4-o)O}2TiCp 2] (2), are reported. The heterometallacyclic ring in 2 contains 12 atoms.
dc.description.versionArticle
dc.identifier.citationJournal of the Chemical Society, Dalton Transactions
dc.identifier.citation11
dc.identifier.issn1470479X
dc.identifier.urihttp://hdl.handle.net/10019.1/12987
dc.subjectAromatic hydrocarbons
dc.subjectCoordination reactions
dc.subjectCrystal structure
dc.subjectMolecular structure
dc.subjectRate constants
dc.subjectLigands
dc.subjectOrganometallics
dc.titleMono- and bi-dentate Group 6-coordinated and titanium-containing isocyanide ligands prepared from benzoxazole
dc.typeArticle
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