Mono- and bi-dentate Group 6-coordinated and titanium-containing isocyanide ligands prepared from benzoxazole
Date
2002
Authors
An J.
Van Niekerk L.
Esterhuysen C.
Raubenheimer H.G.
Journal Title
Journal ISSN
Volume Title
Publisher
Abstract
Reaction of lithiated benzoxazole with Group 6 carbonyl complexes and subsequently with Cp2TiCl2 affords bimetallic systems in which the titanium is O-bonded and the Group 6 metal isocyanide-coordinated. Depending on starting material and reaction conditions the cyclopentadienyl titanium complex may act as either a mono- or bi-dentate ligand. Crystal and molecular structures of [(CO)5Cr{CN(C6H4-o)O}Ti(Cl)Cp2] (1) and [(CO)4Cr-{CN(C6H4-o)O}2TiCp 2] (2), are reported. The heterometallacyclic ring in 2 contains 12 atoms.
Description
Keywords
Aromatic hydrocarbons, Coordination reactions, Crystal structure, Molecular structure, Rate constants, Ligands, Organometallics
Citation
Journal of the Chemical Society, Dalton Transactions
11
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