Transient chirality in a distal-substituted resorcinarene metal complex
Date
2010
Authors
Kleinhans D.J.
Arnott G.E.
Journal Title
Journal ISSN
Volume Title
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Abstract
A novel distal bidentate S/S resorcinarene ligand has been synthesised and a bis-μ-chloro-bridged palladium(ii) complex obtained. The solid state structure for this complex represents the first crystal structure evidence for a bispalladium-μ-chloro-bridged complex bound to thioether ligands. Furthermore, solution NMR studies revealed conformational changes in the flexible resorcinarene ligand and discreet transient chirality around the sulfur centres. © The Royal Society of Chemistry 2010.
Description
Keywords
Conformational change, Palladium complexes, Resorcinarene, Solid-state structures, Solution NMR, Thioether ligands, Chirality, Crystal structure, Enantiomers, Ligands, Metal complexes, Palladium, Stereochemistry, Sulfur, Palladium compounds
Citation
Dalton Transactions
39
25
39
25