Initialisation in RAFT-mediated polymerisation of methyl acrylate

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dc.contributor.authorMcLeary J.B.
dc.contributor.authorMcKenzie J.M.
dc.contributor.authorTonge M.P.
dc.contributor.authorSanderson R.D.
dc.contributor.authorKlumperman B.
dc.date.accessioned2011-05-15T16:01:23Z
dc.date.available2011-05-15T16:01:23Z
dc.date.issued2004
dc.description.abstractInhibition in Reversible Addition-Fragmentation chain Transfer (RAFT)-mediated polymerisations is currently a controversial issue; here we provide evidence that the slow "propagation" of the initiating and leaving group radicals during the early part (the period of consumption of the initial RAFT agent) of methyl acrylate RAFT-mediated polymerisation has characteristics similar to inhibition.
dc.description.versionArticle
dc.identifier.citationChemical Communications
dc.identifier.citation10
dc.identifier.citation17
dc.identifier.issn13597345
dc.identifier.other10.1039/b404857a
dc.identifier.urihttp://hdl.handle.net/10019.1/11953
dc.subjectacrylic acid methyl ester
dc.subjectfunctional group
dc.subjectradical
dc.subjectaddition reaction
dc.subjectarticle
dc.subjectfragmentation reaction
dc.subjectpolymerization
dc.subjectreaction analysis
dc.subjectreversible addition fragmentation chain transfer
dc.titleInitialisation in RAFT-mediated polymerisation of methyl acrylate
dc.typeArticle
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