Aerial oxidation of tetrahydrofuran to 2-hydroxotetrahydrofuran in the presence of a trimeric CuI complex [Cu3L3] (HL = tBuNHC(S)NHP(S)(OiPr)2) and trapping of the unstable product at recrystallization

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dc.contributor.authorLuckay R.C.
dc.contributor.authorSheng X.
dc.contributor.authorStrasser C.E.
dc.contributor.authorRaubenheimer H.G.
dc.contributor.authorSafin D.A.
dc.contributor.authorBabashkina M.G.
dc.contributor.authorKlein A.
dc.date.accessioned2011-05-15T16:05:14Z
dc.date.available2011-05-15T16:05:14Z
dc.date.issued2010
dc.description.abstractThe reaction of the potassium salt of N-thiophosphorylated thiourea tBuNHC(S)NHP(S)(OiPr)2 (HL) with Cu(NO3)2 in aqueous EtOH leads to the trinuclear [Cu3(tBuNHC(S)NP(S)(OiPr) 2-S,S′)3] ([Cu3L3]) complex. It was established that [Cu3L3] provokes the aerobic oxidation of tetrahydrofuran to 2-hydroxotetrahydrofuran and traps the latter at crystallization. © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique.
dc.description.versionArticle
dc.identifier.citationNew Journal of Chemistry
dc.identifier.citation34
dc.identifier.citation12
dc.identifier.issn11440546
dc.identifier.other10.1039/c0nj00314j
dc.identifier.urihttp://hdl.handle.net/10019.1/13034
dc.subject2 hydroxotetrahydrofuran
dc.subjectcopper complex
dc.subjecttetrahydrofuran
dc.subjectthiourea
dc.subjectunclassified drug
dc.subjectabsorption spectroscopy
dc.subjectActinomyces
dc.subjectaqueous solution
dc.subjectarticle
dc.subjectcatalysis
dc.subjectcrystallization
dc.subjectelectrospray mass spectrometry
dc.subjectgas chromatography
dc.subjecthydrogen bond
dc.subjectinfrared spectroscopy
dc.subjectnonhuman
dc.subjectoxidation
dc.subjectphosphorus nuclear magnetic resonance
dc.subjectphosphorylation
dc.subjectpriority journal
dc.subjectproton nuclear magnetic resonance
dc.subjectsynthesis
dc.subjectultraviolet spectroscopy
dc.subjectX ray diffraction
dc.titleAerial oxidation of tetrahydrofuran to 2-hydroxotetrahydrofuran in the presence of a trimeric CuI complex [Cu3L3] (HL = tBuNHC(S)NHP(S)(OiPr)2) and trapping of the unstable product at recrystallization
dc.typeArticle
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