Selectivity and structure of mixed guest clathrates

Simple item page
dc.contributor.authorLe Roex T.
dc.contributor.authorNassimbeni L.R.
dc.contributor.authorWeber E.
dc.date.accessioned2011-05-15T16:05:14Z
dc.date.available2011-05-15T16:05:14Z
dc.date.issued2008
dc.description.abstractThis study investigates the selectivity of two organic host molecules towards pairs of guest molecules and in particular describes the crystal structures of the mixed guest clathrates obtained in selectivity studies. The diol organic host compounds 9,9′-(biphenyl-4,4′-diyl)difluoren-9-ol (H1) and 9,9′-(ethyne-1,2-diyl)difluoren-9-ol (H2) investigated in this study were found to show interesting selectivities (determined via competition experiments) towards THF vs. Et2O and EtOH vs. MeCN, respectively. The crystal structures of the single guest inclusion compounds were elucidated and compared and in addition the crystal structures of the inclusion compounds containing mixed guests were studied and in each case could be correlated with the selectivity profiles. © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique.
dc.description.versionArticle
dc.identifier.citationNew Journal of Chemistry
dc.identifier.citation32
dc.identifier.citation5
dc.identifier.issn11440546
dc.identifier.other10.1039/b718397f
dc.identifier.urihttp://hdl.handle.net/10019.1/13038
dc.subject9,9' (biphenyl 4,4' diyl)difluoren 9 ol
dc.subject9,9' (ethyne 1,2 diyl)difluoren 9 ol
dc.subjectalcohol
dc.subjectether
dc.subjectorganic compound
dc.subjecttetrahydrofuran
dc.subjectarticle
dc.subjectcrystal structure
dc.subjecthydrogen bond
dc.subjectpriority journal
dc.subjectstoichiometry
dc.subjectstructure analysis
dc.titleSelectivity and structure of mixed guest clathrates
dc.typeArticle
Files
Collections
Stellenbosch University - Scopus Publications