Hexakis(1H-imidazole-N 3)cobalt(III) tris-(hexa- fluoridophosphate) hexa-hydrate
dc.contributor.author | Surdykowski A. | |
dc.contributor.author | Czkowska A. | |
dc.contributor.author | Dobrzaska L. | |
dc.contributor.author | Szyk E. | |
dc.date.accessioned | 2011-05-15T15:56:17Z | |
dc.date.available | 2011-05-15T15:56:17Z | |
dc.date.issued | 2009 | |
dc.description.abstract | In the crystal structure of the title compound, [Co(C3H 4N2)6](PF6)3·6H2O, the CoIII atom lies on a special position with site-symmetry and the P atom is located on a special position with site symmetry . The CoIII atom has an almost ideal octa-hedral coordination formed by the N atoms of six imidazole ligands. The water mol-ecules form hydrogen-bonded helical chains propagating in [001] by O- H⋯O inter-actions with a distance of 2.913 (2) Å. They simultaneously inter-act as hydrogen-bond acceptors and donors with the cations and anions, respectively, resulting in the formation of a three-dimensional assembly. Weak C- H⋯F inter-actions further stabilize the crystal structure. | |
dc.description.version | Article | |
dc.identifier.citation | Acta Crystallographica Section E: Structure Reports Online | |
dc.identifier.citation | 65 | |
dc.identifier.citation | 10 | |
dc.identifier.issn | 16005368 | |
dc.identifier.other | 10.1107/S160053680903863X | |
dc.identifier.uri | http://hdl.handle.net/10019.1/9769 | |
dc.title | Hexakis(1H-imidazole-N 3)cobalt(III) tris-(hexa- fluoridophosphate) hexa-hydrate | |
dc.type | Article |