Synthesis and characterisation of thiolato Schiff base nickel(n) complexes. X-Ray structures of Ni(η5-C5H5)(PPh3)(SC 6H4N=CHC6-H4Br-4′) and Ni(η5-C5H5)(PBu3)(SC 6H4N=CHC6H4CH3-4′)

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dc.contributor.authorNevondo F.A.
dc.contributor.authorCrouch A.M.
dc.contributor.authorDarkwa J.
dc.date.accessioned2011-05-15T16:05:08Z
dc.date.available2011-05-15T16:05:08Z
dc.date.issued2000
dc.description.abstractA series of complexes of formula Ni(η5-C5H5)(PR3)(SC 6H4N=CHC6H4X-4′) (R = Ph, Bu; X = F, Cl, Br, CH3, OH, H) has been isolated from the reactions of Ni(η5-C5H5)(PPh3)Cl or the bromo derivative, the thiol Schiff base ligands, 4-HSC6H4N=CHC6H4X-4′, and triethylamine. Preliminary thermal analysis data indicate that the PBu3 complexes could exhibit liquid crystalline behaviour. Electrochemistry of the PPh3 compounds gave irreversible redox couples, in contrast to the quasi-reversibility of the PBu3 compounds. © The Royal Society of Chemistry 2000.
dc.description.versionArticle
dc.identifier.citationJournal of the Chemical Society, Dalton Transactions
dc.identifier.citation1
dc.identifier.issn1470479X
dc.identifier.urihttp://hdl.handle.net/10019.1/12990
dc.titleSynthesis and characterisation of thiolato Schiff base nickel(n) complexes. X-Ray structures of Ni(η5-C5H5)(PPh3)(SC 6H4N=CHC6-H4Br-4′) and Ni(η5-C5H5)(PBu3)(SC 6H4N=CHC6H4CH3-4′)
dc.typeArticle
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