Penta-carbonyl-2 κ5C-chlorido-1κCl-bis- [1(η5)-cyclo-penta-dien-yl][2-oxido(meth-yl)methyl- ene-1:22 O:C]tungsten(0)zirconium(IV)
dc.contributor.author | Esterhuysen C. | |
dc.contributor.author | Neveling A. | |
dc.contributor.author | Luruli N. | |
dc.contributor.author | Kruger G.J. | |
dc.contributor.author | Cronje S. | |
dc.date.accessioned | 2011-05-15T15:56:19Z | |
dc.date.available | 2011-05-15T15:56:19Z | |
dc.date.issued | 2008 | |
dc.description.abstract | The title compound, [ZrW(C5H5)2(C2H3O)Cl(CO)5] or [W(CO)5C(CH3)OZr(C5H5) 2Cl], consists of two metal centres, with a (tungsten penta-carbon-yl)oxymethyl- carbene group coordinating as a monodentate ligand to the chloridozirconocene. The two halves of the mol-ecule are related by a crystallographic mirror plane. Delocalization through the Zr - O - C=W unit is indicated by a short Zr - O distance and a nearly linear Zr - O - C angle. | |
dc.description.version | Article | |
dc.identifier.citation | Acta Crystallographica Section E: Structure Reports Online | |
dc.identifier.citation | 64 | |
dc.identifier.citation | 10 | |
dc.identifier.issn | 16005368 | |
dc.identifier.other | 10.1107/S1600536808028006 | |
dc.identifier.uri | http://hdl.handle.net/10019.1/9779 | |
dc.title | Penta-carbonyl-2 κ5C-chlorido-1κCl-bis- [1(η5)-cyclo-penta-dien-yl][2-oxido(meth-yl)methyl- ene-1:22 O:C]tungsten(0)zirconium(IV) | |
dc.type | Article |