Penta-carbonyl-25 C-chlorido-1Cl-bis-[1(5)-cyclo- penta-dien-yl]( - Oxido-benzyl-idene-1:2κ2 O:C)titanium(IV) tungsten(0)

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dc.contributor.authorEsterhuysen C.
dc.contributor.authorNel I.B.J.
dc.contributor.authorEsterhuysen M.W.
dc.contributor.authorCronje S.
dc.date.accessioned2011-05-15T15:56:18Z
dc.date.available2011-05-15T15:56:18Z
dc.date.issued2008
dc.description.abstractThe title compound, [TiW(C5H5)2(C7H5O)Cl(CO)5], consists of two metal centres, with a (tungstenpenta-carbon-yl)oxy-phenyl-carbene unit coordinated by a titanocene chloride. The oxycarbene group is nearly planar, with the phenyl ring twisted by an angle of 39.1 (2)° with respect to this plane. One of the cyclo-penta-dienyl rings undergoes an offset face-to-face π-π inter-action [3.544 (6) Å] with the symmetry-related cyclo-penta-dienyl ring of a neighbouring mol-ecule. © 2008.
dc.description.versionArticle
dc.identifier.citationActa Crystallographica Section E: Structure Reports Online
dc.identifier.citation64
dc.identifier.citation12
dc.identifier.issn16005368
dc.identifier.other10.1107/S1600536808036465
dc.identifier.urihttp://hdl.handle.net/10019.1/9775
dc.titlePenta-carbonyl-25 C-chlorido-1Cl-bis-[1(5)-cyclo- penta-dien-yl]( - Oxido-benzyl-idene-1:2κ2 O:C)titanium(IV) tungsten(0)
dc.typeArticle
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