Templating polymerization of dodecylammonium surfactants with polymerizable (meth)acrylate counter ions
dc.contributor.author | Hartmann P.C. | |
dc.contributor.author | Sanderson R.D. | |
dc.date.accessioned | 2011-05-15T15:57:12Z | |
dc.date.available | 2011-05-15T15:57:12Z | |
dc.date.issued | 2005 | |
dc.description.abstract | Both dodecylammonium acrylate (I) and dodecylammonium methacrylate (II) are reactive surfactants in which the polymerizable group is the organic counterion. Templating polymerization of I and II from the lyotropic liquid crystalline (LLC) lamellar phase was successfully performed with conservation of the supramolecular structure. A 20 wt% aqueous solution of II formed cubic bicontinuous phases, even upon addition of divinyl benzene (DVB). Polymerization from the cubic phases was attempted without and with DVB (3 wt%). Bicontinuous cubic phases always evolved toward lamellar structures upon polymerization. © 2005 International Union of Pure and Applied Chemistry. | |
dc.description.version | Conference Paper | |
dc.identifier.citation | Macromolecular Symposia | |
dc.identifier.citation | 225 | |
dc.identifier.issn | 10221360 | |
dc.identifier.other | 10.1002/masy.200550718 | |
dc.identifier.uri | http://hdl.handle.net/10019.1/10267 | |
dc.subject | Critical micelle concentration | |
dc.subject | Ions | |
dc.subject | Polymerization | |
dc.subject | Protons | |
dc.subject | Self assembly | |
dc.subject | Supramolecular chemistry | |
dc.subject | X ray scattering | |
dc.subject | Cubic phase | |
dc.subject | Dodecylammonium acrylate | |
dc.subject | Lyotropic liquid crystalline (LLC) | |
dc.subject | Templates | |
dc.subject | Surface active agents | |
dc.title | Templating polymerization of dodecylammonium surfactants with polymerizable (meth)acrylate counter ions | |
dc.type | Conference Paper |