Gold acyl complex formation and decarbonylation during indene synthesis from catalytically active vinylidene complexes

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raubenheimer_gold_2015.pdf(313.3 KB)
Date
2015-04
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Publisher
Wiley
Abstract
The development of targeted gold acyl complexes, which are generated from dialkynes via vinylidene intermediates, and can decarbonylate to form indenes by proto-aurolysis is highlighted.
Description
CITATION: Raubenheimer, Helgard G. 2015. Gold acyl complex formation and decarbonylation during indene synthesis from catalytically active vinylidene complexes. ChemCatChem, 7(8), doi: 1002/cctc.201500092.
The original publication is available at http://onlinelibrary.wiley.com/journal/10.1002/(ISSN)1867-3899
Keywords
Gold, Decarbonylation, Indenes, Synthetic methods, Vinylidenes
Citation
Raubenheimer, Helgard G. 2015. Gold acyl complex formation and decarbonylation during indene synthesis from catalytically active vinylidene complexes. ChemCatChem, 7(8), doi: 1002/cctc.201500092
URI
http://hdl.handle.net/10019.1/96458
Collections
Research Articles (Chemistry and Polymer Science)