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Kinetic and mechanistic features of nitroxide mediated (co)polymerization
(Stellenbosch : University of Stellenbosch, 2011-03)
Please refer to full text to view abstract.
Polypropylene/filler nanocomposites by melt compounding and in situ polymerization
(Stellenbosch : University of Stellenbosch, 2010-12)
ENGLISH ABSTRACT: The properties of polymer nanocomposites depend greatly on the
chemistry of the polymer matrices, the nature of the nanofillers, and the way in
which they are prepared. Understanding the synthesis–str ...
Hydrophobic core/shell particles via miniemulsion polymerization
(Stellenbosch : University of Stellenbosch, 2006-12)
Hydrophobic core/shell latex particles were synthesized for use in barrier coatings using the
miniemulsion polymerization process. Particles with liquid or with hard cores were
successfully synthesized using miniemulsion ...
The synthesis of 1-butene oligomers with vinyl endgroups and their use in further reactions
(Stellenbosch : University of Stellenbosch, 2007-03)
This study comprises the synthesis, functionalization, and characterization of 1-butene
oligomers, as well as the synthesis of oligobutene-based macro-RAFT agent.
The directed oligomerization of 1-butene was carried out ...
Synthesis and characterization of glycopolymer brushes
(Stellenbosch : University of Stellenbosch, 2010-12)
ENGLISH ABSTRACT: Please refer to full text for abstract
Preparation of polymer-clay nanocomposites via dispersion polymerization using tailor-made polymeric surface modifiers
(Stellenbosch : Stellenbosch University, 2011-12)
ENGLISH ABSTRACT: Fully exfoliated polystyrene-clay nanocomposites were prepared via free radical polymerization in dispersion polymerization, in a mixture of ethanol and water. Sodium montomorillonite clay (MMT) was ...
The use of chromium/bis(diphenylphosphino)amine catalysts in tandem ethylene copolymerization processes
(Stellenbosch : Stellenbosch University, 2012-03)
ENGLISH ABSTRACT: The possibility of utilizing the chromium/bis(diphenylphosphino)amine (PNP) type of
catalysts in ethylene polymerization processes was investigated. These processes
include the production of linear low ...
Polymerization and oligomerization reactions mediated by metallodendrimers of zinc and palladium
(Stellenbosch : Stellenbosch University, 2012-03)
ENGLISH ABSTRACT: Please refer to full text for abstract
Poly(N-vinylpyrrolidone) - Poly(γ-benzyl-L-glutamate) conjugates
(Stellenbosch : Stellenbosch University, 2012-03)
ENGLISH ABSTRACT: The combination of natural and synthetic polymers allow for the synthesis of advanced
hybrid copolymers. These hybrid copolymers have applications in biomedical areas, one
such area being in drug delivery ...
Design, synthesis and characterization of novel raft agents
(Stellenbosch : University of Stellenbosch, 2005-12)
This thesis begins with the description of the preparation of thirteen dithioesters (of the form Z-
(C=S)-S-R) which were characterized via Fourier-transform infrared spectroscopy (FT-IR), nuclear
magnetic resonance ...