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A study on the reversible photo-induced isomerisation of platinum(II) and palladium(II) complexes of the N,N-dialkyl-N’-acyl(aroyl)thioureas with reversed-phase HPLC separation from related rhodium(III), ruthenium(III) and iridium(III) complexes
(Stellenbosch : Stellenbosch University, 2014-04)
ENGLISH ABSTRACT: See item for full text
Reversible photo-induced isomerization of cis-[M(L-κS,O)2] (M=PdII, PtII) complexes with N,N-dialkyl-N’-acyl(aroyl)thiourea ligands (HL): Key to the isolation of novel geometric trans-[M(L-κS,O)2] and trans-[M(L-κS,N)2] isomers
(Stellenbosch : Stellenbosch University, 2018-03)
ENGLISH ABSTRACT: The reaction of a series of selected N,N-dialkyl-N’-acyl(aroyl)thioureas to PtII or PdII formed exclusively cis-[M(Ln -κS,O)2] complexes which were fully characterized by melting point determination, 1H, ...