Neutral palladium(II) complexes with P,N Schiff-base ligands : synthesis, characterization and application as Suzuki-Miyaura coupling catalysts
Date
2012-02-22
Authors
Mahamo T.
Mogorosi M.M.
Moss J.R.
Mapolie S.F.
Chris Slootweg J.
Lammertsma K.
Smith G.S.
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Abstract
Palladium(II) complexes of the general formulae [PdCl
2(P
∧N)] and [Pd(Me)Cl(P
∧N)] were obtained from bidentate ligands bearing phosphine and imine donor groups. The complexes were shown to be highly active catalysts for the Suzuki-Miyaura cross-coupling reaction. The complexes are tolerant of a wide variety of reaction conditions such as solvent, choice of base as well as substituents on both arylboronic acids and aryl halides. © 2012 Elsevier B.V. All rights reserved.
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Journal of Organometallic Chemistry