ITEM VIEW

Solid-state dynamics of porous materials

dc.contributor.advisorBarbour, L. J.en_ZA
dc.contributor.advisorEsterhuysen, C.en_ZA
dc.contributor.authorGrobler, Ilneen_ZA
dc.contributor.otherStellenbosch University. Faculty of Science. Dept. of Chemistry and Polymer Science.en_ZA
dc.date.accessioned2013-11-19T10:34:39Zen_ZA
dc.date.accessioned2014-01-21T09:25:33Zen_ZA
dc.date.accessioned2014-07-10T09:35:40Z
dc.date.available2015-11-19T03:00:09Z
dc.date.issued2013-12en_ZA
dc.identifier.urihttp://hdl.handle.net/10019.1/95478
dc.descriptionThesis (PhD)--Stellenbosch University, 2013.en_ZA
dc.description.abstractENGLISH ABSTRACT: A number of porous metal-organic and organic crystalline materials were prepared with a view to study the solid-state dynamics involved in sorption and guest-exchange processes. The main goal was to gain an understanding of the mechanisms involved in structural changes induced by external stimuli. To this end, single-crystal X-ray diffraction (SCD) experiments were carried out under variable temperature and pressure conditions, supplemented by thermal analysis and sorption experiments.en_ZA
dc.description.abstractAFRIKAANSE OPSOMMING: 'n Aantal poreuse metaal-organiese en organiese kristallyne materiale is berei met die doel om die vaste-toestand dinamika wat betrokke is in sorpsie en gas-uitruil (E. guest-exchange) prosesse te ondersoek. Die hoofdoel is om 'n begrip van die meganismes wat betrokke is in die strukturele veranderinge veroorsaak deur eksterne stimuli, te verkry. Dus is enkel-kristal X-straal-diffraksie eksperimente uitgevoer onder verskeie temperatuur- en drukkondisies. Die X-straal diffraksie eksperimente is aangevul deur termo-analise (E. thermal analysis) en sorpsie eksperimente.af_ZA
dc.format.extentxii, 214 pages, illustrationsen_ZA
dc.language.isoen_ZAen_ZA
dc.publisherStellenbosch : Stellenbosch Universityen_ZA
dc.subjectPorosityen_ZA
dc.subjectSupramolecular chemistryen_ZA
dc.subjectCrystal engineeringen_ZA
dc.subjectInclusion compoundsen_ZA
dc.subjectAbsorptionen_ZA
dc.subjectPorous materialsen_ZA
dc.subjectGuest-exchange processen_ZA
dc.subjectDissertations -- Chemistry and Polymer Scienceen_ZA
dc.titleSolid-state dynamics of porous materialsen_ZA
dc.typeThesisen_ZA
dc.rights.holderStellenbosch Universityen_ZA
dc.embargo.terms2015-11-19en_ZA


Files in this item

Thumbnail
Thumbnail
Thumbnail

This item appears in the following Collection(s)

ITEM VIEW