Mono- en dikernige karbeenkomplekse van Mn(I) en W(O)

Neveling, Arno (1999-12)

Thesis (M.Sc.) -- University of Stellenbosch, 1999.

Thesis

ENGLISH SUMMARY: In the first part of this thesis zirconocene complexes with anionic Mn(I) and W(O) Fischer-type carbene complexes as ligands are described. The catalytic activity of the zirconocene W(O) carbene complex was tested as well. The second section of this study comprises a report on novel thiazolinylidene complexes of Mn(I), prepared via protonation or alkylation from thiazolyl complexes.

AFRIKAANSE OPSOMMING: In die eerste deel van hierdie verhandeling word die bereiding van anioniese Fischer-tipe wolfram(O)- en mangaan(I)karbeenkomplekse as ligande vir sirkoniumverbindings beskryf. Die aldus gevormde sirkonium-W(O)karbeenkompleks se katalitiese aktiwiteit is ondersoek. Die tweede deel bevat 'n beskrywing van nuwe tiasolinilideenkomplekse van Mn(I) wat via alkilering of protonering van tiasolielkomplekse berei is.

Please refer to this item in SUNScholar by using the following persistent URL: http://hdl.handle.net/10019.1/70246
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