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New ligands for gold : bonding mode and structural complex characterisation
(Stellenbosch : Stellenbosch University, 2008-12)
Novel gold(I) trithiophosphite complexes were synthesised by utilising the ligands P(SR)3 (R = Me, Ph) and 1,2-bis(1,3,2-dithiaphospholan-2-ylthio)ethane (2L). Reaction with (tht)AuCl or (tht)AuC6F5 readily yielded the ...
High resolution NMR studies concerning the solvation/hydration and coordination chemistry of Pt (II/IV) compounds
(Stellenbosch : Stellenbosch University, 2005-12)
ENGLISH ABSTRACT: Pt(JV) complexes with S, 0-donating aroylthioureas have been synthesized by oxidative addition of elemental halogens to the Pt(JJ) precursors, leading to the first-reported crystal structures of Pt(JV) ...