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Electrolytes for redox flow battery systems
(Stellenbosch : University of Stellenbosch, 2010-03)
Electrochemical behaviour of Ce, Fe, Cr,V and Mn in the presence of DTPA, EDTA, EDDS,
NTA ligands were investigated by using cyclic voltammetry, a rotating disc electrode and
electrochemical impedance spectroscopy for ...
The preparation and characterization of multinuclear catalysts based on novel dendrimers : application in the oligomerization and polymerization of unsaturated hydrocarbons
(Stellenbosch : University of Stellenbosch, 2011-03)
In this thesis we describe the application of novel salicylaldimine and iminopyridyl
nickel metallodendrimer complexes as catalysts in the transformation of á-olefins as well as
in the polymerization of norbornene.
New ...
Synthesis and characterization of multiphase copolymers
(Stellenbosch : Stellenbosch University, 2011-12)
ENGLISH ABSTRACT: Multiphase copolymers generally consist of copolymers where the disparate natures of each
of the segments results in complex phase-segregated morphologies in the solid state. The
outstanding properties ...
Electrospinning of polyacrylonitrile nanofibres with additives : study of orientation and crystallinity
(Stellenbosch : University of Stellenbosch, 2010-03)
ENGLISH ABSTRACT:
Polyacrylonitrile, (PAN), polymers are of interest due to their many unique characteristics in comparison
to most other fibre forming polymers. The focus of this study was the effect of electrospinning ...
Photoelectrochemical detection of inorganic mercury in aqueous solutions
(Stellenbosch : University of Stellenbosch, 2010-12)
ENGLISH ABSTRACT: Due to the adverse human health effects associated with mercury (Hg) toxicity, an
innovative method for inorganic mercury (Hg2+) determination in aqueous solutions
was investigated. The method of Hg2+ ...
Oxazoline directed lithiation of Calix[4]arene and Ferrocene
(Stellenbosch : Stellenbosch University, 2011-12)
ENGLISH ABSTRACT: The use of chiral oxazoline directed lithiation provides a highly diastereoselective (up to >99%
de) route to meta functionalised inherently chiral calixarenes. This methodology can be used on
both the ...
Investigation into the semiochemical communication involved in neonatal offspring recognition in sheep
(Stellenbosch : University of Stellenbosch, 2010-03)
ENGLISH ABSTRACT:
Sheep husbandry substantially contributes to South Africa’s economy. Lamb
mortality is regarded as a major constraint to sustainable sheep production, and an
important factor in lamb survival is the ...
Chemical characterisation of the aroma of honeybush (Cyclopia) species
(Stellenbosch : University of Stellenbosch, 2010-12)
ENGLISH ABSTRACT:
Honeybush tea, also known as “South Africa’s sweetest tea”, is a herbal tea made from the
leaves and twigs of Cyclopia spp., indigenous to the fynbos biome in the Western and Eastern Cape
provinces of ...
Analysis of vegetable oils, seeds and beans by TGA and NMR spectroscopy
(Stellenbosch : University of Stellenbosch, 2011-03)
ENGLISH ABSTRACT: Due to the commercial, nutritional and health value of vegetable oils, seeds and beans, the
analysis of their components is of much interest. In this dissertation oil-containing food
products, specifically ...
Comprehensive multidimensional gas chromatography for the analysis of Fischer-Tropsch products
(Stellenbosch : Stellenbosch University, 2011-12)
ENGLISH ABSTRACT: The analysis of Fischer–Tropsch–derived (FT–derived) synthetic crude and derived products
is very challenging because of the highly complex nature of these products. In this study, the
use of comprehensive ...