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Utilisation of various bonding modes of nitrogen-rich heterocycles in gold(I) chemistry
(Stellenbosch : University of Stellenbosch, 2006-03)
This study describes the exploitation of numerous donor ligand possibilities presented by
selected nitrogen-rich heterocyclic ligands towards gold(I). The preparation and structural
characterisation of novel gold(I) ...
Structure-function relationships of bolaamphiphilic peptides and peptide hybrids
(Stellenbosch : University of Stellenbosch, 2006-12)
Synthetic peptides derived from the active core of a natural antimicrobial peptide were used as
a template for the design of novel bolaamphiphilic peptides and hybrid molecules. The amphiphilic
character of the original ...
A multinuclear magnetic resonance spectroscopy study of E/Z configurational isomers of unsymmetrical N-alkyl-N-alkyl(aryl)-N'-acylthioureas of platinum(II) complexes
(Stellenbosch : Stellenbosch University, 2006-12)
ENGLISH ABSTRACT: The partial double bond character of the carbon-nitrogen bond of the (S)C-NRR’ moiety results in unsymmetrical
dialkyl-substituted N-alkyl-N-alkyl(aryl)-N’-acylthioureas, R”C(O)NHC(S)NRR’ (HL) displaying ...