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Now showing items 21-30 of 35
Structure/property relationships of commercial propylene/1-pentene random copolymers
(Stellenbosch : University of Stellenbosch, 2006-03)
Propylene/1-pentene random copolymers are a relatively new family of random copolymers being prepared by Sasol Polymers and reveals high impact strength, good tensile properties, excellent optical properties, good rheological ...
Reversible addition fragmentation chain transfer (RAFT) mediated polymerization of N-vinylpyrrolidone
(Stellenbosch : University of Stellenbosch, 2008-03)
Xanthate-mediated polymerization was investigated as a tool for the preparation
of well-defined poly(N-vinylpyrrolidone) and copolymers of N-vinylpyrrolidone. Some
results regarding the monomer vinyl acetate are included, ...
The effect of the crystalline state on the properties of the dative bond
(Stellenbosch : Stellenbosch University, 2005-12)
ENGLISH ABSTRACT: Density functional theory (DFT) has been used to investigate the effect of
the surrounding molecules on the structure of selected boron-nitrogen compounds.
It was found that a very limited number of ...
Synthesis and characterization of tailored polyurethane coatings
(Stellenbosch : University of Stellenbosch, 2005-12)
Aqueous polyurethane (PU) dispersions were synthesized for use in paper coatings. These
PUs contained a polyester polyol soft segment (content of between 65 to 75%) and a
urethane hard segment (content of between 30 to ...
Self-healing coatings based on thiol-ene chemistry
(Stellenbosch : University of Stellenbosch, 2009-03)
The work presented in this dissertation describes the development of self-healing
coatings based on thiol-ene chemistry. The approach was to synthesize capsules with
thiol and ene compounds separately encapsulated. These ...
Mechanistic studies of reversible addition-fragmentation chain transfer mediated polymerization
(Stellenbosch : Stellenbosch University, 2004-03)
ENGLISH ABSTRACT: To comply with the ever growing demands for materials with better properties and complex architectures,
polymer chemistry has resorted to the use of living free radical polymerization techniques. Despite ...
The structure-property relationships of polyolefins
(Stellenbosch : University of Stellenbosch, 2009-03)
Polypropylene is an extremely versatile material and has a broad spectrum of
applications due to the variations in properties which are possible with this material. The
variations in the properties of the material are ...
Synthesis and characterisation of amphiphilic block copolymers
(Stellenbosch : University of Stellenbosch, 2005-03)
This study involves the synthesis and characterisation of PEG-based amphiphilic block
copolymers for the hydrophilization of polysulphone ultrafiltration membranes. PEG
based macro RAFT agents were synthesized and ...
Novel siloxane block copolymers
(Stellenbosch : Stellenbosch University, 2008-12)
The research presented in this dissertation was concerned with the living radical
polymerization (LRP) of an amphiphilic, water-soluble, bi-substituted and
biologically compatible acrylamide derivative, namely ...
Synthesis of acrylate-based polymeric and polymerisable surfactants and their application in the emulsion polymerisation of styrene
(Stellenbosch : University of Stellenbosch, 2006-03)
The study described in this dissertation examines the synthesis of mainly acrylate-based surfactants and their subsequent use as emulsifiers/stabilisers in the emulsion polymerisation of styrene. Some acrylamide-based ...