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Utilisation of various bonding modes of nitrogen-rich heterocycles in gold(I) chemistry

Gabrielli, William Fullard (Stellenbosch : University of Stellenbosch, 2006-03)

This study describes the exploitation of numerous donor ligand possibilities presented by selected nitrogen-rich heterocyclic ligands towards gold(I). The preparation and structural characterisation of novel gold(I) ...

A multinuclear magnetic resonance spectroscopy study of E/Z configurational isomers of unsymmetrical N-alkyl-N-alkyl(aryl)-N'-acylthioureas of platinum(II) complexes

Mtongana, Sibusiso (Stellenbosch : Stellenbosch University, 2006-12)

ENGLISH ABSTRACT: The partial double bond character of the carbon-nitrogen bond of the (S)C-NRR’ moiety results in unsymmetrical dialkyl-substituted N-alkyl-N-alkyl(aryl)-N’-acylthioureas, R”C(O)NHC(S)NRR’ (HL) displaying ...