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Utilisation of various bonding modes of nitrogen-rich heterocycles in gold(I) chemistry
(Stellenbosch : University of Stellenbosch, 2006-03)
This study describes the exploitation of numerous donor ligand possibilities presented by
selected nitrogen-rich heterocyclic ligands towards gold(I). The preparation and structural
characterisation of novel gold(I) ...
Structure-function relationships of bolaamphiphilic peptides and peptide hybrids
(Stellenbosch : University of Stellenbosch, 2006-12)
Synthetic peptides derived from the active core of a natural antimicrobial peptide were used as
a template for the design of novel bolaamphiphilic peptides and hybrid molecules. The amphiphilic
character of the original ...
Novel analytical approaches for studying degradation in polypropylene and propylene-1-pentene copolymers
(Stellenbosch : University of Stellenbosch, 2006-03)
Commercial polyolefins degrade under the influence of light, heat, chemical and mechanical factors. They are therefore stabilised to ensure that they maintain performance characteristics during their service life. Degradation ...
New monomer for hydrophobic acrylic copolymers and their novel properties
(Stellenbosch : University of Stellenbosch, 2006-12)
The synthesis and characterization of a new tertiary alcohol (2-octyl-2-dodecanol) and “bushy-tailed”, hydrophobic acrylic monomer (2-octyl-dodecyl acrylate) from a 1-decene dimer (2-octyl-1-dodecene) precursor that was ...
Structure/property relationships of commercial propylene/1-pentene random copolymers
(Stellenbosch : University of Stellenbosch, 2006-03)
Propylene/1-pentene random copolymers are a relatively new family of random copolymers being prepared by Sasol Polymers and reveals high impact strength, good tensile properties, excellent optical properties, good rheological ...
Synthesis, structure and coordination chemistry of new monopodal and bipodal thiocarbamic esters and acyl(aroyl)-substituted ureas with Ni(II), Pd(II), Pt(II) and Cu(II)
(Stellenbosch : Stellenbosch University, 2006-12)
ENGLISH ABSTRACT: N-acyl(aroyl)-N',N'-dialkylthioureas have resulted in a number of potential industrial and analytical applications within the platinum group metals (PGM) industry. N-acyl(aroyl)thiocarbamic-0-alkyl
esters ...
Synthesis of acrylate-based polymeric and polymerisable surfactants and their application in the emulsion polymerisation of styrene
(Stellenbosch : University of Stellenbosch, 2006-03)
The study described in this dissertation examines the synthesis of mainly acrylate-based surfactants and their subsequent use as emulsifiers/stabilisers in the emulsion polymerisation of styrene. Some acrylamide-based ...
A multinuclear magnetic resonance spectroscopy study of E/Z configurational isomers of unsymmetrical N-alkyl-N-alkyl(aryl)-N'-acylthioureas of platinum(II) complexes
(Stellenbosch : Stellenbosch University, 2006-12)
ENGLISH ABSTRACT: The partial double bond character of the carbon-nitrogen bond of the (S)C-NRR’ moiety results in unsymmetrical
dialkyl-substituted N-alkyl-N-alkyl(aryl)-N’-acylthioureas, R”C(O)NHC(S)NRR’ (HL) displaying ...