RAFT mediated polysaccharide copolymers

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dc.contributor.advisor Sanderson, R. D.
dc.contributor.advisor McLeary, J. B.
dc.contributor.advisor Grumel, V.
dc.contributor.author Fleet, Reda en_ZA
dc.contributor.other University of Stellenbosch. Faculty of Science. Dept. of Chemistry and Polymer Science.
dc.date.accessioned 2008-07-09T09:33:39Z en_ZA
dc.date.accessioned 2010-06-01T08:51:18Z
dc.date.available 2008-07-09T09:33:39Z en_ZA
dc.date.available 2010-06-01T08:51:18Z
dc.date.issued 2006-12 en_ZA
dc.identifier.uri http://hdl.handle.net/10019.1/2526
dc.description Thesis (MSc (Chemistry and Polymer Science))--University of Stellenbosch, 2006.
dc.description.abstract Cellulose, one of the most abundant organic substances on earth, is a linear polymer of D-glucose units joined through 1,4-β-linkages. Cellulose is however not easily processed without chemical modification. A number of techniques exist for the modification of cellulose, of which the viscose process is one of the most widely applied. Grafting of synthetic polymeric chains onto or from cellulosic materials is an useful technique that can be used to combine the strengths of synthetic and natural polymers dramatically, so changing the properties of cellulosic materials (pulp, regenerated cellulose, cellulose derivatives). In this study five model xanthate (Reversible Addition-Fragmentation chain Transfer (RAFT)/Macromolecular Design through Interchange of Xanthates (MADIX)) agents, namely, monofunctional, difunctional, trifunctional and tetrafunctional species of the form S=C(O-Z)-S-R, with different leaving groups and different activating moieties, were prepared and then studied to determine the feasibility of cellulose modification via addition fragmentation processes. These agents were characterized by Nuclear Magnetic Resonance spectroscopy (NMR), Fourier Transform Infrared spectroscopy (FT-IR) and Ultraviolet spectroscopy (UV). Polyvinyl acetates (PVAc) in the form of linear, three armed and four armed star shaped polymers were then successfully synthesized in reactions mediated by these xanthate RAFT/MADIX agents Xanthates were applied to polysaccharide materials using the viscose process (xanthate esters were formed directly on a cellulosic substrate, with subsequent alkylation) Grafting reactions were then conducted with the polysaccharides; cellulose was modified with vinyl acetate, [this is an example of a surface modification of natural polymers that is of interest in various industries, such as textiles and paper manufacture]. Analysis of the graft copolymers was conducted via Size Exclusion Chromatography (SEC), Liquid Adsorption Chromatography (LAC), Thermogravimetric Analysis (TGA), and FT-IR. Polyvinyl acetate was successfully grafted onto three polysaccharides (cellulosic materials), namely Hydroxyl Propyl Cellulose (HPC), Methyl Cellulose (MC) and cellulose. The study showed that the modification of cellulosic substrates with defined grafts of vinyl acetate can be easily achieved through minor modifications to existing industrial techniques. en_ZA
dc.language.iso en en_ZA
dc.publisher Stellenbosch : University of Stellenbosch
dc.subject RAFT en_ZA
dc.subject Polysaccharide en_ZA
dc.subject Graft copolymers en_ZA
dc.subject Xanthate en_ZA
dc.subject Addition polymerization en_ZA
dc.subject Dissertations -- Polymer science en_ZA
dc.subject Theses -- Polymer science en_ZA
dc.subject.other Chemistry and Polymer Science en_ZA
dc.title RAFT mediated polysaccharide copolymers en_ZA
dc.type Thesis en_ZA
dc.rights.holder University of Stellenbosch
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