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Nuwe reaksies van gedeprotoneerde Fischer-tipe karbeenkomplekse
This study comprises the preparation and characterisation of completely new Fischer-type carbene complexes of chromium and tungsten by deprotonation of (CO)5M=C(NMe2)(Me), (CO)5M=C(OMe)(Me) or (CO)5M=C(NMe2)C≡CH, and ...
Hard-hard and soft-soft coordination in complexes of Group 6 and Group 10 & 11 metals respectively
In this study, the coordination of certain Group 6 and Group 10 & 11 metals to Odonor and S-donor ligands were investigated. For the most part, this involved the isolation of new Mo(VI) and W(VI) complexes. By using a ...
Metal carboxylate complexes relevant to the Fischer-Tropsch synthesis
(Stellenbosch : Stellenbosch University, 2005-03)
In a Fischer-Tropsch refinery environment carboxylate complexes are of interest since the carboxylic acids present in product streams lead to formation of carboxylate salts through leaching of process equipment and catalysts. ...